Material Safety Data Sheet Black Magic
ADM Material Safety Data Sheet
Black Magic
ISSUE DATE:
October 2003
REVISION DATE:
June 2007
MATERIAL SAFETY DATA SHEET
Black Magic
COMPANY DETAILS
COMPANY NAME:
ADM – Australian Dental Manufacturing
ACN: 010 967 432
ADDRESS:
3
Papps
Crt
Redwood Park
SA
5097
TELEPHONE:
08-82635585
FAX:
08-82635598
EMAIL:
admchief PLEASE REMOVE ALL CAPITALS@PLEASE
REMOVE ALL CAPITALSbigpond.net.au
EMERGENCY TELEPHONE NUMBER: 131 126
PRODUCT INFORMATION
PRODUCT NAME:
Black Magic
OTHER NAMES:
None
UN NUMBER:
1133
DANGEROUS GOODS CLASS:
3
SUB RISK CLASS:
Not Available
HAZCHEM CODE:
3[Y]E
POISON SCHEDULE:
S5
PRODUCT USE:
Polyether Tray Adhesive
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ADM Material Safety Data Sheet
Black Magic
COMPOSITION
Chemical Composition CAS number
Proportion
HAZARDOUS INGREDIENTS:
Acetone
67-64-1
15 – 40%
N-Hexane
110-54-3
5 - 15%
Hexane Isomers
N/A
15 – 40%
Toluene
108-88-3
5 – 15%
Adhesive + Resin N/A
Remainder
PHYSICAL AND CHEMICAL DATA
APPEARANCE:
Grey/Black Liquid
ODOUR:
Solvent odour
MELTING POINT:
Not Available
BOILING POINT:
Not Available
VAPOUR PRESSURE
2.2kPa@15°C (toluene); 180mmHg@20°C
SPECIFIC GRAVITY:
<1
FLASH POINT:
-17°C (Acetone)
AUTO-IGNITION TEMPERATURE 225°C – based on N-hexane
FLAMMABLE LIMITS
LEL: 2%
UEL: 13%
CORROSIVENESS:
Not Corrosive
SOLUBILITY:
Immiscible in Water
MISCIBILITY:
Miscible in Water
pH:
Not Relevant
HEALTH HAZARDS IDENTIFICATION
This Product is classified as hazardous according to criteria of NOHSC.
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ADM Material Safety Data Sheet
Black Magic
ACUTE EFFECTS
INGESTION:
• Harmful if swallowed. May cause irritation to the mouth
and gastro-intestinal tract. Early symptoms likely to be
nausea, abdominal irritation, pain, vomiting, diarrhoea,
headache, pulmonary irritation.
EYE:
• May cause severe eye irritation with discomfort.
SKIN:
• May cause skin irritation. Prolonged occupational exposure
may lead to dermatitis.
INHALED:
• Harmful if inhaled. Inhalation of high vapour concentrations
may cause dizziness, headache, nausea, anaesthetic effects,
central nervous system depression, peripheral neuropathy
(numbness in limbs). Prolonged exposure to vapours may
cause loss of consciousness and death.
CHRONIC EFFECTS:
• The substance is toxic to kidneys, liver, lungs, and the
nervous system. Repeated or prolonged inhalation of
vapours may lead to chronic respiratory irritation. Repeated
or prolonged exposure to the product ingredients can
produce target organs damage. Chronic overexposure may
cause arrhythmia’s (heart beat irregularity) and peripheral
nervous system effects. Prolonged skin contact may cause
dermatitis with drying or cracking of the skin.
• Inflammation of the eye is characterized by redness,
OVEREXPOSURE:
watering, and itching.
• Skin inflammation is characterized by itching, scaling,
reddening. Inhalation of vapours may cause dizziness, an
irregular heartbeat, narcosis, nausea or asphyxiation.
FIRST AID
INGESTION:
• If swallowed, immediately give copious quantities of water.
• Do not induce vomiting. If vomiting occurs, ensure persons
airway is clear and breathing of liquid/foam does not occur.
Never give anything by mouth to an unconscious person.
Call a Physician if symptoms persist.
EYE:
• Irrigate the eye with copious amounts of water for 15
minutes keeping eyelids open. Seek medical assistance if
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ADM Material Safety Data Sheet
Black Magic
symptoms persist.
SKIN:
• Remove contaminated clothing immediately.
• Wash skin with large amounts of soap and water until no
evidence of product remains, at least 15 minutes. Wash clothing
before re-use. If irritation or pain persists – seek medical
attention.
INHALED:
• If inhaled, immediately remove to fresh air until fully
recovered. Monitor for respiratory distress. If not
breathing, give artificial respiration. If breathing is
difficult, give oxygen if qualified to do so.
• Call a Physician.
SCHEDULED POISONS: This Product is a Scheduled Poison.
EXPOSURE CONTROLS/PERSONAL PROTECTION
In accordance with the criteria of NOHSC this Product is classified as hazardous. No exposure limits
are assigned for this specific material by the NOHSC. However the product contains a number of
volatile ingredients. Their exposure limits are:
Name of volatile chemical CAS No.
Proportion Exposure Limits
Acetone
67-64-1
15-40%
TWA: 500ppm; STEL: 1000ppm {1997};
ACGIH (TLV): CEIL 1000ppm [1989}
N-Hexane 110-54-3
5-15%
TWA:
176
mg/m3; 50ppm ACGIH (TLV)
STEL: 1000ppm; TWA: 200ppm DFG
MAK’s
Hexane Isomers
N/A
15-40%
TWA: 1760 mg/m3; CEIL: 3500mg/m3
ACGIH (TLV)
TWA: 500ppm; STEL: 1000ppm ACGIH
(TLV); TWA 200ppm DFG MAK’s
Toluene
108-88-3
5-15%
TWA: 100ppm; STEL: 150ppm
OSHA(PEL) & NIOSH
TWA: 50ppm ACGIH (TLV)
Engineering Controls/Personal Protection
Good work practices can help reduce hazardous exposures and are better than personal protective
equipment. It is recommended to provide local exhaust ventilation at the site of chemical release.
Using respirators or protective equipment is less effective however if necessary use an approved
respirator complying to AS 1716 and used in accordance with AS 1715.
Avoid skin contact wear solvent resistant gloves and clothing. Wear splash proof chemical goggles or
face shield.
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ADM Material Safety Data Sheet
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COMBUSTIBILITY
FIRE HAZARD &
• Highly flammable liquid.
EXPLOSION:
• Isolate from sources of heat, naked flames or sparks.
• If leakage of a container occurs evacuate the area.
• The container may release flammable vapours at ambient
temperatures and readily forms a flammable mixture with air.
Vapours are heavier than air and may travel long distances to
a point of ignition and flash back. If practical remove the
container outside and/or cut off gas supply if safe to do so –
do not endanger life.
• Container may explode in heat or fire. Use water to keep the
container cool. Notify emergency services.
• For small fires use dry chemical, CO
2 or foam extinguishers
• Containers may explode in fire.
Combustion Products
• The ingredients will breakdown under fire conditions.
Decomposition products are Carbon Dioxide, Water Vapour,
traces of Carbon Monoxide. Fumes, smoke and Carbon
Monoxide can be formed during incomplete combustion.
• Fire fighters may need self-containing breathing apparatus.
ACCIDENTAL RELEASE MEASURES
• Avoid accidents, clean up immediately.
• Wear protective equipment to prevent skin and eye contact.
• Wipe up small spills with paper toweling and dispose to bin. Disposal of waste must be in
accordance with the Local Waste Disposal Authority.
• Prevent runoff to drains leading to waterways.
• Wash contaminated area liberally with water.
• For large spills or leaks in confined areas explosive conditions may occur, restrict persons not
wearing protective equipment from the area of spill or leak until cleanup is complete.
• Ventilate the area of spill or leak.
• Water spray may be used to disperse vapours.
• Absorb liquids in vermiculite, dry sand, earth or inert material and deposit in an appropriate
waste disposal container.
• For large spills or leaks it may be necessary to dispose of the product as a Hazardous waste.
Contact your local EPA or authority for specific recommendations.
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ADM Material Safety Data Sheet
Black Magic
HANDLING & STORAGE
• Product to be handled only by qualified staff in dental offices/laboratories.
• See product instructions for safe use
• Store in a cool well ventilated place out of direct sunlight.
• Store away from strong oxidizing agents and acids.
• Store below 25°C keep away from sources of heat; do not drop.
• Protect containers from physical damage, check regularly for leaks.
• Avoid contact with skins and eyes.
• Avoid breathing vapours
• Do not store together with food.
• Comply with the current issue of the Australian Code for the Transportation of Dangerous
Goods by Road and Rail and with the relevant Dangerous Goods Legislation in each State or
Territory.
Risk Phrases
R10: Flammable
R26: Harmful by inhalation
R36: Irritating to eyes
R38: Irritating to skin
Safety Phrases
S2: Keep out of reach of children
S16: Keep away from sources of ignition – no smoking
S23: Do not breath gas/fumes/vapour/spray
S23/24/25: Avoid contact with skin and eyes and breathing vapours
S29 Do not empty into drains
S33 Take precautionary measures against static discharges
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
STABILITY & REACTIVITY
REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid contact with incompatible materials.
INCOMPATIBLES: Flammable in the presence of reducing agents and oxidizing agents.
Avoid contact with strong oxidisers such as Chlorine, Fluorine,
Bromine because violent reactions occur.
The Toluene component may react violently with strong oxidizing
acids such as Sulphuric and Nitric Acids.
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ADM Material Safety Data Sheet
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TOXICOLOGICAL INFORMATION
SYMPTOMS: No adverse health effects are expected if this product is handled in accordance
with this Material Safety Data Sheet and the Product label/instructions.
If the product is spilled or mishandled, the following symptoms may occur:
Short Term Acute Effects:
INGESTION: Irritation to the mouth and gastro-intestinal tract. Nausea, abdominal irritation,
pain vomiting, diarrhea and headache.
EYE CONTENT: Eye irritation with discomfort.
SKIN CONTACT: May cause irritation, prolonged use may cause dermatitis.
INHALATION: Inhalation of high vapour concentrations may cause dizziness, headache, nausea,
anaesthetic effects, central nervous system depression, peripheral neuropathy
(numbness in limbs). Prolonged exposure to vapours may cause loss of
consciousness and death.
.
Long Term Effects:
No specific data is available for this product however the following information on the ingredients are
presented.
Toluene
Oral LD50 (Rat) 2,600mg/kg
Skin (Rabbit) 12,200 mg/kg
Inhalation (Mouse) 7523 ppm (4 hours)
Long term occupational skin exposure to Toluene and Hexane has reportedly caused dermatitis and
cracking of the skin.
It may cause damage to the developing fetus. Toluene should be handled as a Teratogen with extreme
caution. Repeated exposure is toxic to blood, kidneys, lungs, liver, the nervous system, upper
respiratory tract, skin. N-hexane is a neurotoxin.
No other long term effects have been reported for the other ingredients.
ECOLOGICAL INFORMATION
• Spillages from the small packaging of this product are unlikely to penetrate soils. The
solvents used in this product are volatile and will partition to the atmosphere.
• The adhesive component will harden quickly and remain inert with no water-soluble material
to leach into the environment.
• Unlikely to cause long term adverse effects in the environment. This material is not expected
to bioaccumulate.
• As it is likely to vaporize quickly it is unlikely to reach waterways to cause long-term effect
to the aquatic environment. No specific toxicity data to aquatic organisms is available for this
product.
• The ingredients are completely biodegradable.
• No long-term persistent effects are expected.
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ADM Material Safety Data Sheet
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DISPOSAL CONSIDERATIONS
Dispose spill material in accordance with Local Waste Disposal Authority.
Dispose containers thoughtfully to landfill.
TRANSPORT INFORMATION
Classified as a highly flammable liquid gas for transport (ADG, UN, IATA)
UN Number:
1133
DANGEROUS GOODS CLASS:
3
PACKAGING GROUP
II
SUB RISK CLASS:
Nil
HAZCHEM CODE:
3[Y]E
Product is not regulated for shipping. No special storage or transport requirements are necessary.
REGULATORY INFORMATION
From information available, this Product is not classified according to the criteria of NOHSC.
CONTACT POINT
CONTACT: Business Hours: 08 82635585
Mobile: 0419665074
Emergency 131 126
This MSDS summarises our best knowledge of the health and safety hazard information of this
Product and how to safely handle and use the product in the workplace.
Each user should read this MSDS and consider the information in the context of how the Product will
be handled and used in the workplace including its use in conjunction with other products.
If clarification of any term in this MSDS or further information is required to ensure safe use of this
Product can be made the user should contact ADM – Australian Dental Manufacturing
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ADM Material Safety Data Sheet
Black Magic
OTHER INFORMATION
This MSDS is prepared in accordance with the document “National Code of Practice for the
Preparation of Material Safety Data Sheets”, 1994, Worksafe Australia.
Contact Points: Australia
Police & Fire: 000
National Poisons Information Centre: 131126 (anywhere in Australia)
READ LABEL CAREFULLY BEFORE USING PRODUCT
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